V. Aradhya and L. Venkataraman, Single-molecule junctions beyond electronic transport, Nature Nanotechnology, vol.294, issue.6, p.399, 2013.
DOI : 10.1126/science.1064354

P. Batra, Q. Darancet, J. S. Chen, J. R. Meisner, J. B. Widawsky et al., , p.6233, 2013.

J. Tao, Nat. Nanotechnol, vol.1, issue.173, 2006.

H. Haick and D. Cahen, Making contact: Connecting molecules electrically to the macroscopic world, Progress in Surface Science, vol.83, issue.4, p.217, 2008.
DOI : 10.1016/j.progsurf.2008.04.002

A. J. Yan, R. Bergren, M. L. Mccreery, P. Della-rocca, P. Martin et al., Activationless charge transport across 4.5 to 22 nm in molecular electronic junctions, Proceedings of the National Academy of Sciences, vol.91, issue.22, p.5326, 2013.
DOI : 10.1002/qua.10436

URL : https://www.pnas.org/content/pnas/110/14/5326.full.pdf

Y. Sayed, J. A. Fereiro, H. Yan, R. L. Mccreery, and A. J. Bergren, Charge transport in molecular electronic junctions: Compression of the molecular tunnel barrier in the strong coupling regime, Proceedings of the National Academy of Sciences, vol.80, issue.2, p.11498, 2012.
DOI : 10.1103/PhysRevB.80.245427

P. Stewart, F. Maya, D. Kosynkin, S. M. Dirk, J. J. Stapleton et al., Direct Covalent Grafting of Conjugated Molecules onto Si, GaAs, and Pd Surfaces from Aryldiazonium Salts, Journal of the American Chemical Society, vol.126, issue.1, p.370, 2004.
DOI : 10.1021/ja0383120

J. Pinson and F. Podvorica, Attachment of organic layers to conductive or semiconductive surfaces by reduction of diazonium salts, Chemical Society Reviews, vol.17, issue.551, p.429, 2005.
DOI : 10.1021/jp027223r

D. Bélanger and J. Pinson, Electrografting: a powerful method for surface modification, Chemical Society Reviews, vol.31, issue.551, p.3995, 2011.
DOI : 10.1016/j.irbm.2010.02.010

O. Lefèvre, P. Segut, S. Jégou, B. Palacin, and . Jousselme, Towards organic film passivation of germanium wafers using diazonium salts: Mechanism and ambient stability, Chemical Science, vol.22, issue.103, p.1662, 2012.
DOI : 10.1021/la060653e

P. Bonifas, R. L. Mccreery, and N. Lett, , p.4725, 2011.

A. J. Yan, R. L. Bergren, and . Mccreery, All-Carbon Molecular Tunnel Junctions, Journal of the American Chemical Society, vol.133, issue.47, p.19168, 2011.
DOI : 10.1021/ja206619a

J. Bergren, R. L. Mccreery, S. R. Stoyanov, S. Gusarov, and A. Kovalenko, Electronic Characteristics and Charge Transport Mechanisms for Large Area Aromatic Molecular Junctions, The Journal of Physical Chemistry C, vol.114, issue.37, p.15806, 2010.
DOI : 10.1021/jp106362q

L. Mccreery, H. Yan, and A. J. Bergren, A critical perspective on molecular electronic junctions: there is plenty of room in the middle, Phys. Chem. Chem. Phys., vol.3, issue.204, p.1065, 2013.
DOI : 10.1021/nn9012687

R. Delamar, J. Hitmi, J. M. Pinson, and . Saveant, Covalent modification of carbon surfaces by grafting of functionalized aryl radicals produced from electrochemical reduction of diazonium salts, Journal of the American Chemical Society, vol.114, issue.14, p.5883, 1992.
DOI : 10.1021/ja00040a074

M. L. Martin, A. Della-rocca, P. Anthore, J. Lafarge, and . Lacroix, Organic Electrodes Based on Grafted Oligothiophene Units in Ultrathin, Large-Area Molecular Junctions, Journal of the American Chemical Society, vol.134, issue.1, p.154, 2012.
DOI : 10.1021/ja209914d

Y. Fave, G. Leroux, H. Trippé, V. Randriamahazaka, J. Noel et al., Tunable Electrochemical Switches Based on Ultrathin Organic Films, Journal of the American Chemical Society, vol.129, issue.7, p.1890, 2007.
DOI : 10.1021/ja068143u

V. Fave, J. Noel, G. Ghilane, H. Trippé-allard, J. Randriamahazaka et al., Electrochemical Switches Based on Ultrathin Organic Films: From Diode-like Behavior to Charge Transfer Transparency, The Journal of Physical Chemistry C, vol.112, issue.47, p.18638, 2008.
DOI : 10.1021/jp806827a

R. Jayasundara, R. J. Cullen, and P. E. Colavita, In Situ and Real Time Characterization of Spontaneous Grafting of Aryldiazonium Salts at Carbon Surfaces, Chemistry of Materials, vol.25, issue.7, p.1144, 2013.
DOI : 10.1021/cm4007537

T. Laforgue, D. Addou, and . Bélanger, Langmuir, vol.21, issue.6855, 2005.

I. Hines, H. Díez-pérez, T. Nakamura, Y. Shimazaki, N. Asai et al., Controlling Formation of Single-Molecule Junctions by Electrochemical Reduction of Diazonium Terminal Groups, Journal of the American Chemical Society, vol.135, issue.9, p.3319, 2013.
DOI : 10.1021/ja3106434

H. Choi, B. Kim, and C. D. Frisbie, Electrical Resistance of Long Conjugated Molecular Wires, Science, vol.117, issue.2, p.1482, 2008.
DOI : 10.1103/PhysRevLett.97.026801

A. Rabson, B. J. Jönsson-Åkerman, A. H. Romero, R. Escudero, C. Leighton et al., Pinholes may mimic tunneling, Journal of Applied Physics, vol.21, issue.5, p.2786, 2001.
DOI : 10.1103/PhysRevB.27.112

L. Perrin, C. J. Verzijl, C. A. Martin, A. J. Shaikh, R. Eelkema et al., Large tunable image-charge effects in single-molecule junctions, van der Zant, and D. Duli?, p.282, 2013.
DOI : 10.1063/1.2894544

H. Choi, C. Risko, M. C. Delgado, B. Kim, J. Brédas et al., Transition from Tunneling to Hopping Transport in Long, Conjugated Oligo-imine Wires Connected to Metals, Journal of the American Chemical Society, vol.132, issue.12, p.4358, 2010.
DOI : 10.1021/ja910547c

S. Chang, Z. Li, C. N. Lau, B. Larade, and R. S. Williams, Investigation of a model molecular-electronic rectifier with an evaporated Ti???metal top contact, Applied Physics Letters, vol.83, issue.15, p.3198, 2003.
DOI : 10.1103/PhysRevB.66.165436

N. Nerngchamnong, L. Yuan, D. Qi, J. Li, D. Thompson et al., The role of van der Waals forces in the performance of molecular diodes, Nature Nanotechnology, vol.4, issue.2, p.113, 2013.
DOI : 10.1021/nn901821h

L. Fisher, A. V. Walker, A. E. Hooper, T. B. Tighe, K. B. Bahnck et al., O-Terminated Organic Monolayers, Journal of the American Chemical Society, vol.124, issue.19, p.5528, 2002.
DOI : 10.1021/ja0123453

K. Ishii, E. Sugiyama, K. Ito, and . Seki, Energy Level Alignment and Interfacial Electronic Structures at Organic/Metal and Organic/Organic Interfaces, Advanced Materials, vol.11, issue.8, p.605, 1999.
DOI : 10.1002/(SICI)1521-4095(199906)11:8<605::AID-ADMA605>3.0.CO;2-Q

U. Zilberman, G. Tisch, W. Shuster, X. Pisula, K. Feng et al., Carbon Nanotube/Hexa-peri-hexabenzocoronene Bilayers for Discrimination Between Nonpolar Volatile Organic Compounds of Cancer and Humid Atmospheres, Advanced Materials, vol.18, issue.11, p.4317, 2010.
DOI : 10.1103/PhysRevLett.90.156401

U. Gozlan, H. Tisch, and . Haick, Tailoring the Work Function of Gold Surface by Controlling Coverage and Disorder of Polar Molecular Monolayers, The Journal of Physical Chemistry C, vol.112, issue.33, p.12988, 2008.
DOI : 10.1021/jp803124j

R. A. Knipp, A. Street, J. Völkel, and . Ho, Pentacene thin film transistors on inorganic dielectrics: Morphology, structural properties, and electronic transport, Journal of Applied Physics, vol.660, issue.1, p.347, 2003.
DOI : 10.1557/PROC-660-JJ7.10.1